Methyl 2-(4,6-dichloro-1,3,5-triazin-2-yl­amino)acetate

نویسندگان

  • Sérgio M. F. Vilela
  • Filipe A. Almeida Paz
  • João P. C. Tomé
  • Verónica de Zea Bermudez
  • José A. S. Cavaleiro
  • João Rocha
چکیده

The title compound, C(6)H(6)Cl(2)N(4)O(2), was prepared by the nucleophilic substitution of 2,4,6-trichloro-1,3,5-triazine by glycine methyl ester hydro-chloride, and was isolated from the reaction by using flash chromatography. The crystal structure at 150 K reveals the presence two crystallographically independent mol-ecules in the asymmetric unit which differ in the orientation of the pendant methoxy-carbonyl group. Each mol-ecular unit is engaged in strong and highly directional N-H⋯N hydrogen-bonding inter-actions with a symmetry-related mol-ecule, forming supra-molecular dimers which act as the synthons in the crystal packing.

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عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009